JEE Advanced levelSingle correct optionDifficulty 3 of 3bn078
Assertion (A): In FeX3OX4 every iron atom has an actual oxidation state of +8/3. Reason (R): FeX3OX4 is the mixed oxide FeO⋅FeX2OX3 with Fe(II) and Fe(III) in the ratio 1:2.
ABoth A and R are true and R is the correct explanation of A
BA is false but R is true
CBoth A and R are true but R is not the correct explanation of A
DA is true but R is false
Answer: B
Charge balance gives an average of 8/3 (1×2+2×3=8 over 3 Fe), but real iron atoms are Fe(II) or Fe(III), never +8/3. So A is false, while R is true.