JEE Main levelSingle correct optionDifficulty 2 of 3ap210
Anisole is nitrated with HNOX3/HX2SOX4. The main products are
A1-methoxy-3-nitrobenzene only
B1-methoxy-2-nitrobenzene and 1-methoxy-4-nitrobenzene
C1-methoxy-3-nitrobenzene and 1-methoxy-4-nitrobenzene
Dnitrobenzene and methanol
Answer: B
The −OCHX3 group donates electrons by resonance and is an ortho/para director. The main products are the 2-nitro and 4-nitro derivatives, and the para isomer predominates.