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JEE Main levelSingle correct optionDifficulty 2 of 3ap176

Assertion (A): 1-Chloropropane gives mainly propan-1-ol with aqueous KOH but mainly propene with alcoholic KOH. Reason (R): Alcoholic KOH contains the alkoxide ion , a stronger base than in water, which favours E2 elimination.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

In water, is heavily solvated and acts mainly as a nucleophile (SN2), giving the alcohol. In ethanol the equilibrium produces , a stronger base, so E2 elimination to propene dominates. Both statements are true and R explains A.
Practice Alcohols, Phenols and Ethers More on Preparation of alcohols including from carbonyls and Grignard

More questions on Preparation of alcohols including from carbonyls and Grignard