JEE Main levelSingle correct optionDifficulty 2 of 3ap101
Aqueous NaHCOX3 is added separately to solutions of phenol, benzoic acid and 2,4,6-trinitrophenol (picric acid, pKa≈0.4). Effervescence of COX2 is seen with
Abenzoic acid and picric acid only
Bbenzoic acid only
Cphenol and benzoic acid only
Dall three
Answer: A
NaHCOX3 releases COX2 only with acids stronger than carbonic acid (pKa≈6.4). Benzoic acid (4.2) and picric acid (0.4) qualify, while phenol (10) is weaker than carbonic acid and does not.