JEE Main levelSingle correct optionDifficulty 2 of 3ap026
Salicylic acid is warmed with ethanoic anhydride in the presence of a few drops of conc. HX2SOX4. The product (aspirin) is
Amethyl 2-hydroxybenzoate
B2-acetoxybenzoic acid
C2-hydroxybenzoyl chloride
D2-hydroxyacetophenone
Answer: B
The phenolic OH is acetylated by the anhydride, giving 2-acetoxybenzoic acid (acetylsalicylic acid). The carboxylic acid group is untouched. Methyl salicylate would need methanol.