JEE Main levelSingle correct optionDifficulty 2 of 3td141
At 298K and constant pressure, NX2(g)+3HX2(g)2NHX3(g) has ΔH=−92.2kJ. Treating the surroundings as a large reservoir at 298K, ΔSsurr is
A+309JK−1
B−309JK−1
C+619JK−1
D+30.9JK−1
Answer: A
The surroundings receive the heat released by the system at constant P, qsurr=−ΔH=+92200J. ΔSsurr=qsurr/T=92200/298=+309JK−1; the sign is positive because heat flows into the surroundings.