JEE Advanced levelSingle correct optionDifficulty 3 of 3td089
For NaCl(s): ΔfH∘=−411, sublimation of Na(s)=+108, ionisation enthalpy of Na(g)=+496, Cl−Cl bond enthalpy =+242, electron gain enthalpy of Cl(g)=−349 (all in kJmol−1). The lattice enthalpy for NaX+(g)+ClX−(g)NaCl(s) is
A−908kJmol−1
B+787kJmol−1
C−787kJmol−1
D−1485kJmol−1
Answer: C
Born-Haber cycle: ΔfH=ΔsubH+IE+21BE+EA+ΔlatH. The energy to make the gaseous ions is 108+496+121−349=376kJ. So ΔlatH=−411−376=−787kJmol−1 (the dissociation of only half a mole of ClX2 is needed).