JEE Main levelOne or more correct optionsDifficulty 2 of 3td026
Which of the following statements about ideal gases is/are correct?
ACP,m−CV,m=R for any ideal gas.
BFor a diatomic gas with only translation and rotation active, γ=7/5.
CFor a rigid linear molecule such as COX2 with vibrations frozen, CV,m=3R.
DAt constant temperature, CP,m of an ideal gas increases with increasing pressure.
Answer: A, B
(A) Mayer's relation: true. (B) CV=25R, CP=27R, γ=7/5: true. (C) A linear molecule has 3 translational and 2 rotational degrees of freedom, so CV=25R (not 3R): false. (D) For an ideal gas CP is independent of pressure: false.