Answer: B
Osmotic pressure is proportional to the number of solute particles per litre, i.e. iw/M. The values are NaCl: 2/58.5=0.0342; urea: 1/60=0.0167; macromolecule: 1/105=1.0×10−5; gold sol: 1/(1.97×108)=5.1×10−9 (mol per litre). The order is NaCl > urea > macromolecule > gold sol.