JEE Advanced levelSingle correct optionDifficulty 3 of 3si215
Ethanol is heated with conc. HX2SOX4 at 443 K to give A. A reacts with BrX2 in CClX4 to give B. B is heated with excess NaNHX2 and then water is added to give C. C is treated with dilute HX2SOX4 and HgSOX4 at 333 K to give D. D is
Aethanol
Bethanal
Cethanoic acid
Dethane-1,2-diol
Answer: B
A is ethene, B is 1,2-dibromoethane and C is ethyne (double dehydrohalogenation). Mercury(II)-catalysed hydration of ethyne gives the enol, which tautomerises to ethanal, CHX3CHO.