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JEE Advanced levelSingle correct optionDifficulty 3 of 3si215

Ethanol is heated with conc. at 443 K to give A. A reacts with in to give B. B is heated with excess and then water is added to give C. C is treated with dilute and at 333 K to give D. D is

  1. Aethanol
  2. Bethanal
  3. Cethanoic acid
  4. Dethane-1,2-diol

Answer: B

A is ethene, B is 1,2-dibromoethane and C is ethyne (double dehydrohalogenation). Mercury(II)-catalysed hydration of ethyne gives the enol, which tautomerises to ethanal, .
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