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JEE Main levelOne or more correct optionsDifficulty 2 of 3si207

Benzenediazonium chloride is prepared from aniline with at 273 K. Which of the following transformations of this salt are correct?

  1. A gives chlorobenzene.
  2. B gives benzene.
  3. CWarming with water gives phenol.
  4. DWarming with aqueous NaOH gives aniline.

Answer: A, B, C

The Sandmeyer reaction with gives chlorobenzene. Hypophosphorous acid reduces the diazonium group to H, giving benzene. Warming with water replaces by OH, giving phenol. The reverse conversion to aniline does not occur, so (D) is wrong.
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