JEE Advanced levelSingle correct optionDifficulty 3 of 3si194
In a Liebig combustion train the tube of anhydrous CaClX2 (absorbs water) is normally placed before the tube of concentrated KOH solution (absorbs COX2, and also absorbs water vapour). If by mistake the KOH tube is placed first, the calculated results will show
Apercentage of C too low and percentage of H too high
Bboth percentages too high
Cno error, because both tubes absorb independently
Dpercentage of C too high and percentage of H too low
Answer: D
The KOH solution absorbs both COX2 and the water vapour. Its mass gain is therefore larger than the COX2 alone (so %C is too high), while the CaClX2 tube now receives little or no water (so %H is too low).