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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3si114

A hydrocarbon X () adds two moles of over Ni to give hexane and, on ozonolysis followed by , gives two moles of ethanal and one mole of ethanedial (). Select the correct statement(s).

  1. AThe degree of unsaturation of X is 2.
  2. BComplete hydrogenation of X gives an unbranched product.
  3. CX gives a white precipitate with ammoniacal .
  4. DX is hexa-2,4-diene.

Answer: A, B, D

Fragments , and joined together give , hexa-2,4-diene. has degree of unsaturation , and hydrogenation gives hexane. It has no terminal alkyne C-H and so does not give a precipitate.
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