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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3si108

Which statements about distillation methods are correct?

  1. AReducing the external pressure lowers the boiling temperature, so heat-sensitive liquids can be distilled.
  2. BAn immiscible organic liquid and water boil together below at 1 atm.
  3. CA fractionating column provides repeated vaporisation-condensation cycles that enrich the vapour in the more volatile component.
  4. DFractional distillation separates the components of a constant-boiling azeotrope into pure liquids.

Answer: A, B, C

Statements 1-3 are the principles of vacuum, steam and fractional distillation. An azeotrope boils at constant composition, so its components cannot be separated by fractional distillation alone.
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