JEE Advanced levelSingle correct optionDifficulty 3 of 3si092
A hydrocarbon CX10HX16 absorbs 2 mol of HX2 over Pt to give CX10HX20, which absorbs no more HX2. The number of rings and the number of pi bonds in the original hydrocarbon are respectively
A2 and 1
B1 and 2
C0 and 3
D3 and 0
Answer: B
CX10HX16 has degree of unsaturation (22−16)/2=3. Each mole of HX2 consumed removes one pi bond, so there are 2 pi bonds. The product CX10HX20 has degree 1, which is one ring that remains. Rings = 3 - 2 = 1.