MolSynapsequestion bank
MolSynapse / Question bank / Stereoisomerism / Chirality, enantiomers and R/S configuration
JEE Main levelSingle correct optionDifficulty 2 of 3st174

Assertion (A): cis-1,2-Dimethylcyclopropane is optically inactive although it contains two stereocentres. Reason (R): The molecule has an internal plane of symmetry that passes through the CH carbon and the midpoint of the C1-C2 bond.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

The cis isomer (1R,2S) has the two methyl groups on the same face of the ring, and the plane through C3 and the midpoint of C1-C2 reflects C1 into C2 (R into S). The molecule is therefore meso and optically inactive. The reason is true and is exactly why the assertion holds.
Practice Stereoisomerism More on Chirality, enantiomers and R/S configuration

More questions on Chirality, enantiomers and R/S configuration