JEE Main levelSingle correct optionDifficulty 2 of 3st129
(R)-X has [α]=−48.0 and (S)-X has [α]=+48.0 (units degree dm−1 (g/mL)−1). A solution contains 0.12 g/mL of (R)-X and 0.04 g/mL of (S)-X and is examined in a 2.0 dm tube. The observed rotation is
A−11.52∘
B+7.68∘
C−7.68∘
D−3.84∘
Answer: C
The rotations add: α=(−48.0)(2.0)(0.12)+(+48.0)(2.0)(0.04)=−11.52+3.84=−7.68∘. Ignoring the (S) component gives −11.52∘, and omitting the tube length gives −3.84∘.