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JEE Advanced levelSingle correct optionDifficulty 3 of 3st080

D-Glucose is an open-chain aldohexose with four stereocentres. How many of its diastereomers belong to the L-series?

  1. A7
  2. B8
  3. C15
  4. D14

Answer: A

There are aldohexose stereoisomers, 8 in the D-series and 8 in the L-series. Excluding D-glucose itself gives 15 other stereoisomers, but L-glucose is its enantiomer and not a diastereomer, so 14 diastereomers remain. Of these, 7 are D-sugars and are L-sugars, so the answer is 7.
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