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JEE Main levelSingle correct optionDifficulty 2 of 3st065

Assertion (A): a compound with n stereocentres always has exactly stereoisomers. Reason (R): each stereocentre can have either the R or the S configuration.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: D

Each centre can indeed be R or S, so R is true and gives an upper limit of . The limit is reached only when the molecule has no symmetry; for example 2,3-dibromobutane has 3 stereoisomers, not 4. Therefore A is false and R is true.
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