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JEE Main levelSingle correct optionDifficulty 2 of 3st031

A Fischer projection of 1-deuterioethanol, , shows the vertical chain, top to bottom: , C1, . On C1 the left group is and the right group is . Using CIP rules (mass number decides between isotopes), the configuration of C1 is

  1. A
  2. Bnot a stereocentre
  3. C
  4. D, because and are identical in priority

Answer: C

Priorities: (carbon outranks hydrogen isotopes, and outranks ). In the projection (left) (top) (bottom) runs clockwise. The lowest priority is on a horizontal bond, so the true sense is reversed: .
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