JEE Main levelSingle correct optionDifficulty 2 of 3st031
A Fischer projection of 1-deuterioethanol, CHX3−CHD−OH, shows the vertical chain, top to bottom: CHX3, C1, D. On C1 the left group is OH and the right group is H. Using CIP rules (mass number decides between isotopes), the configuration of C1 is
AR
Bnot a stereocentre
CS
DR, because D and H are identical in priority
Answer: C
Priorities: OH>CHX3>D>H (carbon outranks hydrogen isotopes, and D outranks H). In the projection OH (left) →CHX3 (top) →D (bottom) runs clockwise. The lowest priority H is on a horizontal bond, so the true sense is reversed: S.