JEE Main levelSingle correct optionDifficulty 2 of 3so136
1.17g of NaCl (molar mass 58.5gmol−1) is dissolved in water to make 500mL of solution at 300K. Assuming complete dissociation and R=0.0821Latmmol−1K−1, the osmotic pressure is
A0.99atm
B3.94atm
C1.97atm
D0.49atm
Answer: C
n=1.17/58.5=0.020 mol and C=0.020/0.500=0.040 M. With i=2, π=iCRT=2×0.040×0.0821×300=1.97 atm. Taking i=1 gives only half this value.