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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3ss181

Which of the following statements about the crystal structure are correct?

  1. AEach has 12 next-nearest neighbours.
  2. BThe 8 tetrahedral voids of the lattice in each cell are all occupied by .
  3. CWhen cations and anions touch along the edge, the cell edge is .
  4. DThe ions occupy all the octahedral voids of the ccp lattice.

Answer: A, C, D

The ions form an fcc array themselves, so each has 12 like neighbours (true). The edge contains ... i.e. one cation diameter and two anion radii, so (true). The 4 octahedral voids hold 4 (true). The tetrahedral voids are empty in rock salt (false).
Practice Solid State More on Ionic solids: NaCl, CsCl, ZnS, CaF2, Na2O structures

More questions on Ionic solids: NaCl, CsCl, ZnS, CaF2, Na2O structures