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Defects in solids
JEE Advanced level
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Difficulty 3 of 3
ss102
A sample of wustite has the composition
Fe
X
0.92
O
. Assuming only
Fe
X
2
+
and
Fe
X
3
+
are present, the percentage of iron present as
Fe
X
3
+
is
A
16.0%
B
8.7%
C
17.4%
D
34.8%
Answer: C
Let
Fe
X
3
+
be
x
per O. Charge balance:
3
x
+
2
(
0.92
−
x
)
=
2
, so
x
=
0.16
. Fraction
=
0.16/0.92
=
0.1739
, i.e. 17.4%.
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