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JEE Main levelSingle correct optionDifficulty 2 of 3ss095

Zinc oxide turns yellow on heating and regains its white colour on cooling. This is because

  1. AAnions leave to form Schottky defects
  2. BSome Zn are oxidised to Zn (metal deficiency)
  3. COxygen enters interstitial sites as O
  4. DZn ions move to interstitial sites and free electrons are trapped there (metal excess)

Answer: D

On heating, ZnO loses oxygen, giving . The extra sit in interstitial sites and their electrons are trapped nearby. This metal-excess defect absorbs visible light and gives the yellow colour.
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