JEE Main levelSingle correct optionDifficulty 2 of 3ss095
Zinc oxide turns yellow on heating and regains its white colour on cooling. This is because
AAnions leave to form Schottky defects
BSome Zn2+ are oxidised to Zn3+ (metal deficiency)
COxygen enters interstitial sites as O2−
DZn2+ ions move to interstitial sites and free electrons are trapped there (metal excess)
Answer: D
On heating, ZnO loses oxygen, giving ZnX1+xO. The extra ZnX2+ sit in interstitial sites and their electrons are trapped nearby. This metal-excess defect absorbs visible light and gives the yellow colour.