JEE Advanced levelOne or more correct optionsDifficulty 3 of 3sb159
Select the correct statement(s) about aqueous sodium hydrogencarbonate at 298 K.
AIts pH is close to the average of pKa1 and pKa2 of carbonic acid, about 8.3.
BWith excess Ca(OH)X2 solution it gives a precipitate of CaCOX3.
CIt reacts with both dilute HCl and aqueous NaOH.
DIt is strongly alkaline with a pH of about 12.
Answer: A, B, C
HCOX3X− is amphiprotic: HCOX3X−+HX+HX2COX3 and HCOX3X−+OHX−COX3X2−+HX2O. Its pH is 21(6.35+10.33)≈8.3, so it is weakly alkaline, not pH 12. With excess lime water, HCOX3X−+OHX−+CaX2+CaCOX3+HX2O precipitates. Three statements are correct.