JEE Advanced levelSingle correct optionDifficulty 3 of 3sb106
Plaster of Paris, (CaSOX4)X2⋅HX2O (Ca 40, S 32, O 16, H 1), sets to a hard mass of gypsum on mixing with water. The mass of water chemically taken up when 5.80 g of plaster of Paris sets completely is
A0.72 g
B0.54 g
C1.08 g
D0.36 g
Answer: C
Setting follows (CaSOX4)X2⋅HX2O+3HX2O2CaSOX4⋅2HX2O. Molar mass of plaster of Paris is 2(136)+18=290, so 5.80 g is 0.0200 mol and it absorbs 3×0.0200=0.0600 mol water, which is 0.0600×18=1.08 g.