JEE Advanced levelSingle correct optionDifficulty 3 of 3sb050
A white solid A decomposes on strong heating to a solid B and a gas C. B reacts vigorously with water giving a suspension D used in whitewashing. Passing C into D first gives A as a milky turbidity, and excess C makes the turbidity clear, giving E. Which statement is correct?
AE is Ca(HCOX3)X2, a stable solid that can be isolated by evaporating the solution.
BE is CaO, formed by the reaction of C with D.
CE is Ca(HCOX3)X2, which exists only in solution, and boiling its solution re-precipitates A.
DE is Ca(HCOX3)X2, and boiling its solution precipitates Ca(OH)X2.
Answer: C
A is CaCOX3, B is CaO, C is COX2 and D is Ca(OH)X2 (limewater). CaCOX3+COX2+HX2OCa(HCOX3)X2 dissolves the precipitate, giving E. Ca(HCOX3)X2 is stable only in solution (temporary hardness), and on boiling it reverses to CaCOX3, COX2 and water.