JEE Advanced levelSingle correct optionDifficulty 3 of 3sb029
A metal M reacts slowly with dry NX2 even at room temperature to give a nitride X. X reacts with water to give a gas that turns moist red litmus blue. Which option gives the flame colour of M and the products of strong heating of its nitrate?
AGolden yellow; NaNOX2 and OX2
BCrimson red; LiNOX2 and OX2
CNo colour; MgO, NOX2 and OX2
DCrimson red; LiX2O, NOX2 and OX2
Answer: D
Among the s-block metals only lithium forms a nitride with NX2 at room temperature: 6Li+NX22LiX3N, and LiX3N+3HX2O3LiOH+NHX3, the basic gas. Lithium gives a crimson-red flame. Its nitrate follows the pattern of group 2: 4LiNOX32LiX2O+4NOX2+OX2, unlike the other alkali nitrates which give nitrites.