JEE Advanced levelSingle correct optionDifficulty 3 of 3sb026
A grey-white solid X is formed when a metal that gives a brick-red flame is heated in hydrogen at about 700K. X reacts violently with water to give a gas Y and a clear solution Z, and Z turns milky when COX2 is passed. Which option gives X and the amount of Y from 0.10 mol of X?
ACaHX2; 0.20 mol of HX2
BBaHX2; 0.20 mol of HX2
CCaHX2; 0.10 mol of HX2
DNaH; 0.10 mol of HX2
Answer: A
The brick-red flame identifies calcium, so X is CaHX2, and Z is limewater, which turns milky with COX2. CaHX2+2HX2OCa(OH)X2+2HX2, so each mole of X gives 2 mol of HX2 and 0.10 mol gives 0.20 mol.