JEE Advanced levelSingle correct optionDifficulty 3 of 3sb013
Sodium hydride (2.4g) is heated with excess COX2 to give sodium formate, which is then heated to give sodium oxalate and hydrogen. Assuming 100% yield in both steps, what mass of sodium oxalate is formed? (H = 1, C = 12, O = 16, Na = 23)
A3.35 g
B8.20 g
C6.70 g
D13.40 g
Answer: C
NaH+COX2HCOONa and 2HCOONaNaX2CX2OX4+HX2. Moles of NaH = 2.4/24=0.10, giving 0.10 mol formate and then 0.050 mol oxalate. Molar mass of NaX2CX2OX4 = 134, so mass = 0.050×134=6.70g.