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JEE Main levelOne or more correct optionsDifficulty 2 of 3ro241

The alkyne shown is reduced by different methods. Select ALL correct statements.

  1. ANa in liquid gives the E alkene.
  2. B over Lindlar catalyst gives the E alkene.
  3. CThe products from Na/ and from Lindlar reduction are diastereomers (geometric isomers) of each other.
  4. DComplete hydrogenation with , Pd/C gives pentane.

Answer: A, C, D

The compound is pent-2-yne. Na/ gives (E)-pent-2-ene (statement 1 true); Lindlar gives the Z alkene, so statement 2 is false. E and Z isomers are geometric diastereomers (true), and exhaustive hydrogenation yields pentane (true).
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