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JEE Main levelSingle correct optionDifficulty 2 of 3ro212

2-Methylcyclohexanone is treated with . Taking the migratory aptitude order secondary alkyl primary alkyl, the major product is

  1. A2-methylcyclohexanol
  2. B7-methyloxepan-2-one
  3. C6-oxoheptanoic acid
  4. D3-methyloxepan-2-one

Answer: B

The more substituted ring carbon (C-2, secondary, bearing CH3) migrates in preference to the CH2 carbon (C-6, primary-like). Oxygen is therefore inserted between C=O and the CHCH3 carbon, so the lactone has the methyl on the carbon attached to ring oxygen: 7-methyloxepan-2-one.
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