JEE Main levelSingle correct optionDifficulty 2 of 3ro206
Acetophenone, CX6HX5−CO−CHX3, is treated with mCPBA. The major product is
Amethyl benzoate, CX6HX5−CO−O−CHX3
Bbenzoic acid
Cphenyl ethanoate, CHX3−CO−O−CX6HX5
Dphenylmethyl ethanoate
Answer: C
The group with the higher migratory aptitude moves to oxygen. Phenyl migrates in preference to methyl, so oxygen is inserted between the phenyl group and the carbonyl carbon, giving phenyl ethanoate (phenyl acetate).