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JEE Main levelSingle correct optionDifficulty 2 of 3ro135

Acetophenone is treated with and excess , and the mixture is then acidified with . The products are

  1. Abenzaldehyde and
  2. Bbenzoic acid and
  3. Cphenylacetic acid and
  4. Dbenzoic acid and

Answer: B

The methyl ketone undergoes the haloform reaction: the is tri-iodinated, the group is displaced by hydroxide, giving the benzoate and iodoform. Acidification liberates benzoic acid; is the yellow precipitate.
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