JEE Main levelSingle correct optionDifficulty 2 of 3ro135
Acetophenone is treated with IX2 and excess NaOH, and the mixture is then acidified with HX3OX+. The products are
Abenzaldehyde and CHX2IX2
Bbenzoic acid and CHIX3
Cphenylacetic acid and CHX3I
Dbenzoic acid and CHX3I
Answer: B
The methyl ketone undergoes the haloform reaction: the CHX3 is tri-iodinated, the −CIX3 group is displaced by hydroxide, giving the benzoate and iodoform. Acidification liberates benzoic acid; CHIX3 is the yellow precipitate.