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Redox titration calculations
JEE Main level
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Difficulty 2 of 3
rx181
20.0 mL of a dilute hydrogen peroxide solution is titrated in acidic medium and requires 16.0 mL of 0.0500 M
KMnO
X
4
. The concentration of
H
X
2
O
X
2
(molar mass 34) in g per litre is:
A
6.8
B
1.36
C
8.5
D
3.4
Answer: D
mmol
MnO
X
4
X
−
= 0.8;
2
MnO
X
4
X
−
+
5
H
X
2
O
X
2
gives mmol
H
X
2
O
X
2
=
0.8
×
2.5
=
2.0
. Molarity = 2.0/20.0 = 0.100 M, so concentration =
0.100
×
34
=
3.4
g/L.
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