JEE Advanced levelNumerical answerDifficulty 3 of 3rg162
For oxygen (a=1.36L2atmmol−2, b=0.0318Lmol−1) the second virial coefficient is B=b−a/RT. At what temperature in K (nearest integer, R=0.0821LatmK−1mol−1) does B equal −20.0mLmol−1?
Numerical answer type, answer in K, tolerance 2.
Answer: 320 K
b−a/RT=−0.0200, so a/RT=0.0318+0.0200=0.0518 and T=0.0518Ra=0.0518×0.08211.36=0.0042531.36=319.8K, i.e. 320K.