JEE Main levelSingle correct optionDifficulty 2 of 3qc188
Assertion (A): In group III, solid or aqueous NHX4Cl is added before NHX4OH, and MgX2+ then stays in solution. Reason (R): NHX4Cl suppresses ionisation of NHX4OH by the common-ion effect, so [OHX−] is low enough that Mg(OH)X2 (larger Ksp) is not precipitated while Fe(OH)X3, Al(OH)X3 and Cr(OH)X3 (very small Ksp) are.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
The common ion NHX4X+ reduces [OHX−] to about 10−6M. The ionic product of Mg(OH)X2 then stays below Ksp, while the group III hydroxides, with Ksp many orders smaller, precipitate. Both true; R explains A.