JEE Main levelSingle correct optionDifficulty 2 of 3qc124
Which single reagent distinguishes SrX2+ from CaX2+ by giving a white precipitate (slowly, on standing) with SrX2+ only, when added to a clear, acid-free aqueous solution of each ion?
Adilute HCl
Baqueous NHX4SCN
Cdilute aqueous ammonia
Da saturated solution of CaSOX4 (gypsum water)
Answer: D
SrSOX4 is much less soluble than CaSOX4. Gypsum water supplies enough sulphate to exceed Ksp of SrSOX4 but not of CaSOX4 (which is already saturated). Dilute HCl, NHX4SCN and dilute ammonia give nothing with either ion.