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JEE Main levelSingle correct optionDifficulty 2 of 3qc124

Which single reagent distinguishes from by giving a white precipitate (slowly, on standing) with only, when added to a clear, acid-free aqueous solution of each ion?

  1. Adilute
  2. Baqueous
  3. Cdilute aqueous ammonia
  4. Da saturated solution of (gypsum water)

Answer: D

is much less soluble than . Gypsum water supplies enough sulphate to exceed of but not of (which is already saturated). Dilute , and dilute ammonia give nothing with either ion.
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More questions on Group V and VI cations (Ba, Sr, Ca, Mg) and NH4+