NEET levelSingle correct optionDifficulty 1 of 3qc114
Which compound is formed as a white crystalline precipitate when NaX2HPOX4 is added to a solution of MgX2+ containing NHX4Cl and NHX4OH?
AMgX3(POX4)X2 only
BMg(NHX4)POX4
CMgCOX3
DMg(OH)X2 only
Answer: B
In the presence of NHX4X+ and NHX3 the phosphate precipitates magnesium as magnesium ammonium phosphate: MgX2++NHX3+HPOX4X2−Mg(NHX4)POX4. This is the standard confirmatory test for group VI.