JEE Main levelSingle correct optionDifficulty 2 of 3qc084
Assertion (A): NiS and CoS are not precipitated by HX2S in dilute HCl, yet once precipitated in ammoniacal medium they do not redissolve in cold dilute HCl.
Reason (R): On standing, freshly precipitated NiS and CoS change to a form with a much lower solubility product.
ABoth A and R are true and R is the correct explanation of A
BBoth A and R are true but R is not the correct explanation of A
CA is true but R is false
DA is false but R is true
Answer: A
The initial (alpha) forms have a Ksp larger than the ionic product in dilute acid, so they do not form in group II. They age to a far less soluble form, whose Ksp is too small for cold dilute HCl to dissolve it. R therefore explains A.