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JEE Main levelSingle correct optionDifficulty 2 of 3qc084

Assertion (A): and are not precipitated by in dilute , yet once precipitated in ammoniacal medium they do not redissolve in cold dilute . Reason (R): On standing, freshly precipitated and change to a form with a much lower solubility product.

  1. ABoth A and R are true and R is the correct explanation of A
  2. BBoth A and R are true but R is not the correct explanation of A
  3. CA is true but R is false
  4. DA is false but R is true

Answer: A

The initial (alpha) forms have a larger than the ionic product in dilute acid, so they do not form in group II. They age to a far less soluble form, whose is too small for cold dilute HCl to dissolve it. R therefore explains A.
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