JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qc040
Select the correct statements about the test for ammonium ion.
AThe test is done on the original solution, since ammonium salts are added during the scheme.
BNessler reagent (KX2[HgIX4] in alkali) gives a brown precipitate/colour of the iodide of Millon's base, HgO⋅Hg(NHX2)I.
CWarming with NaOH releases NHX3, which turns moist red litmus blue.
DThe group III filtrate can be used for the Nessler test with the same significance as the original solution.
Answer: A, B, C
NHX4X++OHX−NHX3+HX2O explains the litmus test, and NHX3 reacts with alkaline [HgIX4]X2− to form the brown Millon-base iodide. Because NHX4Cl and NHX4OH are used as reagents in the scheme, the later filtrates always contain NHX4X+, so statement 4 is false.