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JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qa197

A borax sample is investigated. Which statements are correct?

  1. AWith a copper(II) salt in the oxidising flame, the cold bead is blue
  2. BHeated with ethanol and conc. , its vapour burns with a red flame
  3. COn strong heating it swells and then fuses to a glassy bead containing and
  4. DIts aqueous solution is alkaline because and the weak acid leaves the strong base in solution

Answer: A, C, D

Borax is the salt of a strong base and a weak acid, so hydrolysis gives an alkaline solution. Heating removes water of crystallisation and gives and as a glassy bead, which dissolves metal oxides to give coloured metaborates (, blue when cold). The ethyl borate flame is green-edged, not red.
Practice Qualitative Analysis: Anions More on Independent group: sulphate, phosphate, borate

More questions on Independent group: sulphate, phosphate, borate