JEE Advanced levelSingle correct optionDifficulty 3 of 3qa164
Anhydrous borax, NaX2BX4OX7, is warmed with excess ethanol and concentrated HX2SOX4. Assuming complete conversion, the number of B(OCX2HX5)X3 molecules formed per formula unit of NaX2BX4OX7 and the oxidation state of boron in the ester are:
A2; +3
B4; +2
C4; +3
D1; +3
Answer: C
NaX2BX4OX7+HX2SOX4+5HX2ONaX2SOX4+4HX3BOX3 then HX3BOX3+3CX2HX5OHB(OCX2HX5)X3+3HX2O. Four boron atoms give four ester molecules. In the ester, boron is bonded to three alkoxide oxygens, so its oxidation state is +3.