JEE Advanced levelOne or more correct optionsDifficulty 3 of 3qa160
Select all correct statements about the chromyl chloride test.
AUnder the same conditions NaBr gives red CrOX2BrX2 vapours.
BHgClX2 fails to give the test because, being covalent, it does not supply chloride ions.
CSolid NaCl gives orange-red CrOX2ClX2 vapours when warmed with KX2CrX2OX7 and conc. HX2SOX4.
DChromium stays in the +6 oxidation state in going from dichromate to CrOX2ClX2.
Answer: B, C, D
KX2CrX2OX7+4NaCl+6HX2SOX42CrOX2ClX2+4NaHSOX4+2KHSOX4+3HX2O has no change in oxidation states, and covalent HgClX2 does not ionise. Bromide is simply oxidised to BrX2 (no chromyl bromide test exists), so the last statement is false.