MolSynapsequestion bank
MolSynapse / Question bank / Qualitative Analysis: Anions / Concentrated acid group: halides, nitrate, oxalate
JEE Main levelSingle correct optionDifficulty 2 of 3qa135

Chlorine water is added dropwise, with shaking, to a solution of potassium iodide over a layer of chloroform, and then added in large excess. The chloroform layer is:

  1. Aorange-brown at first, then pale yellow as a bromine compound forms
  2. Bviolet at first, then colourless as is oxidised to (I: 0 to +5)
  3. Cviolet, and it stays violet because chlorine cannot oxidise further
  4. Dcolourless throughout, because chloroform does not extract the product

Answer: B

Chlorine first oxidises iodide to iodine, which dissolves in chloroform to give a violet layer. Excess chlorine oxidises it further: , so iodine goes from 0 to +5 and the layer becomes colourless.
Practice Qualitative Analysis: Anions More on Concentrated acid group: halides, nitrate, oxalate

More questions on Concentrated acid group: halides, nitrate, oxalate