JEE Main levelSingle correct optionDifficulty 2 of 3qa135
Chlorine water is added dropwise, with shaking, to a solution of potassium iodide over a layer of chloroform, and then added in large excess. The chloroform layer is:
Aorange-brown at first, then pale yellow as a bromine compound forms
Bviolet at first, then colourless as IX2 is oxidised to HIOX3 (I: 0 to +5)
Cviolet, and it stays violet because chlorine cannot oxidise IX2 further
Dcolourless throughout, because chloroform does not extract the product
Answer: B
Chlorine first oxidises iodide to iodine, which dissolves in chloroform to give a violet layer. Excess chlorine oxidises it further: IX2+5ClX2+6HX2O2HIOX3+10HCl, so iodine goes from 0 to +5 and the layer becomes colourless.