JEE Advanced levelSingle correct optionDifficulty 3 of 3qa124
A white deliquescent solid X is soluble in water. When heated in a dry tube it evolves a brown gas and a colourless gas that rekindles a glowing splinter, and the residue is yellow while hot and white when cold. The residue dissolves in excess hot aqueous NaOH to give a clear solution. Identify X and the formula and shape of the zinc-containing species in the clear solution.
AZn(NOX3)X2; [Zn(OH)X3]X−, trigonal planar
BPb(NOX3)X2; [Pb(OH)X4]X2−, tetrahedral
CZn(NOX3)X2; [Zn(OH)X4]X2−, tetrahedral
DZn(NOX3)X2; [Zn(OH)X6]X4−, octahedral
Answer: C
Brown NOX2 plus OX2 shows a heavy-metal nitrate: 2Zn(NOX3)X22ZnO+4NOX2+OX2. A residue that is yellow hot and white cold is ZnO (the lead oxide residue stays yellow when cold). Amphoteric ZnO dissolves as ZnO+2OHX−+HX2O[Zn(OH)X4]X2−, a four-coordinate sp3 tetrahedral ion.