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JEE Advanced levelSingle correct optionDifficulty 3 of 3qa124

A white deliquescent solid X is soluble in water. When heated in a dry tube it evolves a brown gas and a colourless gas that rekindles a glowing splinter, and the residue is yellow while hot and white when cold. The residue dissolves in excess hot aqueous NaOH to give a clear solution. Identify X and the formula and shape of the zinc-containing species in the clear solution.

  1. A; , trigonal planar
  2. B; , tetrahedral
  3. C; , tetrahedral
  4. D; , octahedral

Answer: C

Brown plus shows a heavy-metal nitrate: . A residue that is yellow hot and white cold is (the lead oxide residue stays yellow when cold). Amphoteric dissolves as , a four-coordinate tetrahedral ion.
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