JEE Main levelSingle correct optionDifficulty 2 of 3qa115
Green crystals of FeSOX4⋅7HX2O are heated strongly in a dry tube until no further change occurs. The gaseous products of the final decomposition of the anhydrous FeSOX4 (ignoring water vapour) are:
ASOX3 only
BHX2S and SOX2
CSOX2 and OX2
DSOX2 and SOX3 (residue red-brown FeX2OX3)
Answer: D
Anhydrous ferrous sulphate decomposes as 2FeSOX4FeX2OX3+SOX2+SOX3. Iron is oxidised from +2 to +3 and sulphur is reduced from +6 to +4 in SOX2. Hence both SOX2 and SOX3 are evolved and FeX2OX3 is left.