JEE Advanced levelSingle correct optionDifficulty 3 of 3qa014
Ammonium dichromate is heated and the swollen green residue is then fused in a borax bead. The number of electrons transferred per formula unit of the salt in its decomposition (oxidation states of N and Cr taken as -3 and +6 initially) and the colour of the bead are
A6 ; blue
B12 ; green
C3 ; green
D6 ; green
Answer: D
(NHX4)X2CrX2OX7CrX2OX3+NX2+4HX2O. Two Cr go from +6 to +3, gaining 6 electrons, while two N go from -3 to 0, losing 6 electrons, so 6 electrons are transferred. The residue is CrX2OX3, which forms green chromium(III) metaborate in both flames.