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JEE Advanced levelSingle correct optionDifficulty 3 of 3qa014

Ammonium dichromate is heated and the swollen green residue is then fused in a borax bead. The number of electrons transferred per formula unit of the salt in its decomposition (oxidation states of N and Cr taken as -3 and +6 initially) and the colour of the bead are

  1. A6 ; blue
  2. B12 ; green
  3. C3 ; green
  4. D6 ; green

Answer: D

. Two Cr go from +6 to +3, gaining 6 electrons, while two N go from -3 to 0, losing 6 electrons, so 6 electrons are transferred. The residue is , which forms green chromium(III) metaborate in both flames.
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