JEE Main levelSingle correct optionDifficulty 2 of 3qa010
A 1.68 g sample of a white solid is heated strongly. A gas that turns lime water milky is evolved, and water droplets condense on the cool part of the tube. Atomic masses: Na 23, C 12, O 16, H 1. The solid and the mass of the residue (assuming complete decomposition) are
ANaHCOX3, 0.62 g
BNaX2COX3, 0.62 g
CNaX2COX3, 1.06 g
DNaHCOX3, 1.06 g
Answer: D
Water vapour together with COX2 shows a hydrogencarbonate: 2NaHCOX3NaX2COX3+COX2+HX2O. Moles of NaHCOX3 = 1.68/84 = 0.0200, so NaX2COX3 = 0.0100 mol = 0.0100 x 106 = 1.06 g. The mass lost is 0.62 g, which is the distractor. Plain NaX2COX3 does not decompose and gives no water.