JEE Main levelSingle correct optionDifficulty 2 of 3qa006
Assertion: The borax bead test is useful only for salts of some d-block metals, because colourless metals give colourless beads.
Reason: On heating, borax gives BX2OX3, which combines with metal oxides to form coloured metaborates.
ABoth the assertion and the reason are true, and the reason explains the assertion
BBoth the assertion and the reason are true, but the reason does not explain the assertion
CThe assertion is true but the reason is false
DThe assertion is false but the reason is true
Answer: A
Borax loses water and then NaX2BX4OX72NaBOX2+BX2OX3. Acidic BX2OX3 displaces the volatile oxide of the metal salt to give metaborates such as Co(BOX2)X2 and Cu(BOX2)X2, whose colours come from d-d transitions. Ions without such transitions give a colourless bead, so the assertion is a direct consequence of the reason.